Read SCSS structure and naming first: it explains the import order, the glob imports that only gulp builds have, and the BEM names the other pages assume. Several stylesheets from one build covers when a new stylesheet is worth it, and Design tokens as custom properties matters most on a multi-brand site, where it replaces a stylesheet per brand.
The last two are practical: the Bootstrap versions and class names you will meet, and how to defer a stylesheet in a way the site's Content Security Policy allows, with the measurements that show whether it helped.